Engineering Plastics: Properties and Processing

Engineering Plastics: Properties & Processing

A comprehensive guide to the most widely used plastic for injection molding materials in modern manufacturing

In today's manufacturing landscape, selecting the right plastic for injection molding is crucial for product performance, durability, and cost-effectiveness. Engineering plastics offer exceptional mechanical properties, chemical resistance, and versatility, making them indispensable across various industries. This guide explores the most commonly used engineering plastics, their unique characteristics, and optimal processing conditions to help manufacturers make informed decisions when choosing a plastic for injection molding.

From automotive components to electronic enclosures, the right plastic for injection molding can significantly impact product quality and production efficiency. Understanding the specific properties and processing requirements of each material ensures that manufacturers can leverage the full potential of these versatile materials.

PC/ABS

Polycarbonate and Acrylonitrile-Butadiene-Styrene Blend

PC/ABS plastic components showing its application in electronics and automotive parts

Typical Applications

  • Computers and electronic devices
  • Lawn and garden equipment
  • Automotive parts including dashboards
  • Interior trim and wheel covers
  • Various consumer goods and appliances

Chemical & Physical Properties

PC/ABS combines the best properties of both polycarbonate (PC) and acrylonitrile-butadiene-styrene (ABS), making it an excellent plastic for injection molding applications requiring a balance of performance and processability.

This blend offers the easy processability of ABS with the superior mechanical properties and thermal stability of PC. The ratio of PC to ABS can be adjusted to modify the thermal stability characteristics. PC/ABS also exhibits excellent flow properties, which is a key advantage when selecting a plastic for injection molding.

Injection Molding Conditions

  • Drying: Process before molding with less than 0.04% moisture. Recommended conditions: 90~120°C for 2~4 hours.
  • Melting Temperature: 230~300°C
  • Mold Temperature: 50~100°C
  • Injection Pressure: Depends on part design and thickness
  • Injection Speed: As high as possible for optimal results
PC/PBT plastic components demonstrating chemical resistance and durability

PC/PBT

Polycarbonate and Polybutylene Terephthalate Blend

PC/PBT represents a sophisticated blend that combines the best attributes of two high-performance polymers, creating a versatile plastic for injection molding applications requiring both strength and chemical resistance.

Typical Applications

  • Gearboxes and mechanical assemblies
  • Automotive bumpers and exterior parts
  • Chemical processing equipment
  • Components requiring thermal stability
  • Products needing impact resistance and dimensional stability

Chemical & Physical Properties

As a high-performance plastic for injection molding, PC/PBT combines the desirable properties of both polycarbonate (PC) and polybutylene terephthalate (PBT).

This engineering plastic blend offers PC's high toughness and dimensional stability combined with PBT's excellent chemical resistance, thermal stability, and lubricating properties. The resulting material provides a balanced performance profile suitable for demanding applications.

The material maintains good mechanical properties across a range of temperatures, making it suitable for both indoor and outdoor applications where environmental conditions can vary significantly.

Injection Molding Conditions

  • Drying: Process before molding. Recommended conditions: 110~135°C for approximately 4 hours.
  • Melting Temperature: 235~300°C
  • Mold Temperature: 37~93°C
  • Injection Pressure: Depends on part geometry and thickness
  • Injection Speed: As high as possible for best results

HDPE

High-Density Polyethylene

HDPE is one of the most widely used plastics globally, valued for its versatility, cost-effectiveness, and excellent chemical resistance, making it a popular plastic for injection molding across numerous industries.

HDPE plastic products including containers, pipes, and household items

Typical Applications

As a versatile plastic for injection molding, HDPE finds applications in numerous industries due to its favorable combination of properties and cost-effectiveness.

  • Refrigerator containers and food storage solutions
  • Household kitchenware and utensils
  • Sealing caps and closures for various containers
  • Industrial chemical storage tanks
  • Water pipes and plumbing fixtures
  • Automotive fuel tanks and fluid reservoirs

Chemical & Physical Properties

HDPE's unique properties stem from its high degree of crystallinity, which contributes to its characteristics as a high-performance plastic for injection molding.

This high crystallinity results in high density, elevated temperature distortion resistance, rigidity, and excellent tensile strength. HDPE offers superior chemical resistance compared to many other plastics and has greater impermeability than LDPE.

HDPE is classified into three types based on density:

  • Type 1: 0.91~0.925 g/cm³
  • Type 2: 0.926~0.94 g/cm³
  • Type 3: 0.94~0.965 g/cm³

HDPE exhibits good flow properties with a melt flow rate (MFR) ranging from 0.1 to 28. A notable consideration is its susceptibility to environmental stress cracking, which can be mitigated by using lower flow materials and designing parts to minimize internal stresses.

While HDPE resists many solvents at room temperature, it can dissolve in hydrocarbon solvents at temperatures above 60°C. Its solvent resistance is superior to that of LDPE, making it a preferred plastic for injection molding applications involving chemical exposure.

Injection Molding Conditions for HDPE

Proper processing parameters are essential to achieve optimal results when using HDPE as a plastic for injection molding, ensuring both part quality and production efficiency.

Drying Requirements

Generally not required for HDPE due to its low moisture absorption characteristics.

Melting Temperature

180~230°C, with specific settings depending on the exact grade and density of the HDPE being processed.

Mold Temperature

20~40°C. For uniform cooling and cost efficiency, cooling channel diameter should be at least 8mm.

Injection Pressure

Up to 1500 bar (150 MPa) with holding pressure up to 750 bar (75 MPa) depending on part design.

Injection Speed

Rapid injection is recommended for HDPE to ensure proper filling and reduce cycle times.

Runner and Gate Design

Various runner and gate designs are suitable for HDPE. The material's good flow properties make it particularly well-suited for hot runner systems, which can improve efficiency and reduce waste when processing this plastic for injection molding. The distance from cooling channels to the mold surface should not exceed 1.5 times the cooling channel diameter.

LDPE plastic products showing flexibility and formability

LDPE

Low-Density Polyethylene

LDPE is valued for its flexibility, toughness, and ease of processing, making it a versatile plastic for injection molding applications requiring these specific characteristics.

Typical Applications

LDPE's unique combination of flexibility and processability makes it a valuable plastic for injection molding in various consumer and industrial applications.

  • Household bowls and containers
  • Cabinets and storage solutions
  • Pipe fittings and connectors
  • Flexible containers and squeeze bottles
  • Toys and child safety products
  • Covers and protective sleeves

Chemical & Physical Properties

As a widely used plastic for injection molding, LDPE offers a unique set of properties that distinguish it from other polyethylenes and engineering plastics.

Commercial LDPE materials typically have a density ranging from 0.91 to 0.94 g/cm³. One notable characteristic is LDPE's permeability to water vapor and other gases, which influences its suitability for certain applications.

LDPE exhibits a high coefficient of thermal expansion, which makes it less suitable for products requiring dimensional stability over a wide temperature range or for long-term use in high-temperature environments.

Shrinkage rates for LDPE vary with density:

  • 2%~5% for density 0.91~0.925 g/cm³
  • 1.5%~4% for density 0.926~0.94 g/cm³

Actual shrinkage rates depend on specific injection molding parameters. Like HDPE, LDPE is resistant to many solvents at room temperature but can swell in aromatic hydrocarbons and chlorinated solvents. It is also prone to environmental stress cracking, a consideration when selecting LDPE as a plastic for injection molding.

Injection Molding Conditions

Proper processing parameters are essential to maximize the performance of LDPE as a plastic for injection molding, ensuring optimal part quality and production efficiency.

  • Drying: Generally not required for LDPE processing
  • Melting Temperature: 180~230°C
  • Mold Temperature: 20~40°C
  • Cooling System: For uniform cooling and efficiency, cooling channel diameter should be at least 8mm, with distance from channels to mold surface not exceeding 1.5 times channel diameter
  • Injection Pressure: Up to 1500 bar (150 MPa)
  • Hold Pressure: Up to 750 bar (75 MPa)
  • Injection Speed: Recommended to use fast injection rates
  • Runners and Gates: All types can be used; LDPE is particularly suitable for hot runner molds, enhancing its performance as a plastic for injection molding

PEI

Polyetherimide

PEI is a high-performance engineering plastic known for its exceptional thermal stability and mechanical properties, making it a premium plastic for injection molding in demanding applications.

PEI plastic components used in high-temperature and demanding applications

Typical Applications

PEI's exceptional properties make it a specialized plastic for injection molding in applications requiring high performance under extreme conditions.

Automotive Industry

  • Engine components and temperature sensors
  • Fuel and air handling systems
  • Under-the-hood electrical components

Electrical & Electronic Equipment

  • Electrical connectors and terminals
  • Printed circuit boards and components
  • Chip housings and semiconductor equipment
  • Explosion-proof enclosures

Aerospace & Aviation

  • Aircraft interior components
  • Cabin equipment and fixtures
  • Avionics housings

Medical Industry

  • Surgical instruments and tool housings
  • Non-implantable medical devices
  • Laboratory equipment

Chemical & Physical Properties

PEI stands out as a high-performance plastic for injection molding due to its exceptional combination of thermal and mechanical properties.

One of PEI's most notable characteristics is its outstanding high-temperature stability. Even in non-reinforced formulations, PEI maintains excellent mechanical strength and rigidity at elevated temperatures, making it ideal for high-heat applications where other plastics would fail.

PEI also exhibits excellent flame resistance, good chemical resistance, and superior electrical insulation properties. Its glass transition temperature is exceptionally high at 215°C, contributing to its thermal performance capabilities.

This advanced plastic for injection molding offers very low shrinkage rates and excellent isotropic mechanical properties, ensuring dimensional stability and consistent performance across all axes of the molded part.

PEI is inherently flame retardant with a UL94 V-0 rating without the need for additional flame retardant additives, which is a significant advantage for electrical and electronic applications.

The material's combination of high strength, temperature resistance, and dimensional stability makes it a premium choice as a plastic for injection molding in demanding environments where reliability and performance are critical.

Injection Molding Conditions for PEI

Processing PEI requires careful attention to parameters due to its high-performance nature as a plastic for injection molding, ensuring that the material's exceptional properties are maintained in the final part.

Drying Requirements

Critical for PEI. Must be thoroughly dried before processing to less than 0.02% moisture content. Recommended conditions: 150~160°C for 4~6 hours in a desiccant dryer.

Melting Temperature

340~400°C, with the exact temperature depending on the specific grade and part complexity. Higher temperatures may be required for thin-walled sections.

Mold Temperature

130~180°C. Maintaining proper mold temperature is critical for achieving optimal part crystallinity, surface finish, and dimensional stability with this high-performance plastic for injection molding.

Injection Pressure

800~1500 bar (80~150 MPa) depending on part design, wall thickness, and flow length. Higher pressures may be needed for complex geometries.

Injection Speed

Medium to high injection speeds are recommended to ensure proper filling before material solidification, with adjustments based on part design and potential for jetting.

Runner and Gate Design

Large runners and gates are recommended due to higher viscosity compared to other plastics. Hot runner systems are preferred for PEI to maintain material temperature and reduce waste in this premium plastic for injection molding.

Choosing the Right Plastic for Injection Molding

Selecting the appropriate plastic for injection molding is a critical decision that impacts product performance, manufacturing efficiency, and overall cost. Each engineering plastic offers unique advantages, from the versatility of PC/ABS blends to the high-temperature resistance of PEI.

Understanding the specific properties, applications, and processing requirements of each plastic for injection molding ensures that manufacturers can optimize their production processes and create high-quality, durable products that meet the demands of their intended applications.

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